Hi Chris, since this is about data integrity and safety, I'll start with SSDs
The most reliable SSDs are Intel, Samsung and Crucial (possibly Plextor too but it's too early to be sure); generally, the bigger they are in any given range, the faster they operate. I'd not consider anything less than 120GB, 240+ would be better (if money were no object).
Raid 1 is fine
but ideally you would buy a 3rd disk ready to replace a possible failure early on; failures in
any hardware tend to follow the 'bathtub effect', relatively high failures in the first few weeks, tailing off to almost zero failures through Months 2-3 until close to the end of the normal lifespan of the components (3~5 or 5~7 years, depending on drive quality?) then rising sharply again.
Enterprise quality SATA drives are better than standard SATA.
Raid 1 is not a backup alternative, a bad power supply could take out both drives in seconds.
Seasonic and XFX are widely regarded as being the best consumer PSU brands, XFX are made by Seasonic. Some other 'makers' also have a few good PSUs in their ranges, some may even be Seasonic made but it's much more of a crapshoot. BeQuiet have a very good reputation in Europe. A good PSU wattage calculator is here:
http://extreme.outervision.com/psucalculatorlite.jsp
A quality
UPS will cushion your setup from mains power anomalies.
If you use external drives for backup, try to buy 'vanilla' drives/enclosures, the more driver/software/hardware complexities there are, the lower your chances of data recovery from them.
Network-attached storage may be better for local backups.
And an offsite backup is always good!