"Used as valid" in the Code means used as the valid name of a taxon -- a species or a subspecies for a species-group names. I.e., not merely cited as a synonym, or cited as a nominal type species.
As noted by AP Peterson on Zoonomen,
Zimmer 1950 concluded that
Ornismya prasina Lesson 1829 is a junior synonym of
Trochilus mellisugus Linnaeus 1758.
Chlorostilbon was described by Gould in 1853
here, with a single included taxonomic species that Gould called
Chlorostilbon prasinus. (Gould's other
Chorostilbon spp were in later parts of the work.)
Note that, in this work, Gould provided systematically a synonymy for any previously established name that he adopted, where he cited earlier uses of this name, the various combinations in which it had occurred in the literature, and any possible synonym. No such thing here, however. The valid name used for the species was treated exactly as if it had never been used before in the literature.
Gould then started his text with:
In other words, not being able to identify Lesson's bird, Gould
deliberately applied the name
Chlorostilbon prasinus to a bird that he described
expressly as
not agreeing with Lesson's figure of
O. prasina.
As Gould's action was clearly and explicitly deliberate, it cannot be treated as a mistake: Gould's
Chlorostilbon prasinus was NOT intended to be a mere recombination of
Ornismya prasina Lesson 1829, and should not be treated as one.
The type of
Chlorostilbon Gould 1853 is, by monotypy,
Chlorostilbon prasinus Gould 1853.
(Under today's taxonomy,
Chlorostilbon prasinus Gould 1853 is a subjective junior synonym of
Trochilus lucidus Shaw 1812 at species rank, and a subjective junior synonym of
Trochilus pucherani Bourcier & Mulsant 1848 at subspecies rank. This does not, of course, make any of these two nominal species the type of
Chlorostilbon.)