As Alexander says in #2, there is quite a lot of variation in Pochards which are not males in breeding plumage. I can't comment, because I don't know, on whether one reason for this might be inter-breeding one or more generations back - but if this were very common, then wouldn't one expect more aberrant male plumage birds?
I looked through some old photos for birds with a large white face/bill patch and attach photos of one such bird. And then for comparison, equivalent crops of Bitis' bird.
As you can see, some birds have more white-ish behind the bill. However, as I have marked with arrows, there is a thin reddish line from the point at the bottom rear of the bill to the main head colouration (A), and also a reddish patch at the top of the bill before the full rich head colouring is apparent (B).
Both of these features are visible in Bitis' original post, as I indicate in the photos.
It's true that Bitis' bird is exceptionally clearly marked but nonetheless, I suggest, it has a standard face pattern for its type of Pochard.
As an aside, no-one has suggested the possibility that there might be some reason other than hybridisation for this strong marking - e.g. some kind of de-feathering as a result, for example, of mite infestation or similar (the bird reminded me a bit of the face of crows in my area with such a problem).
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Hi MacNara, I think all female Aythya ducks are rather variable in their appearance, depending on one hand on age and on the other hand on time of the year (for example browner with more uniform head in summer for pochard) .
You will have seen also a huge variation in Tufted duck , Greater scaup, Redhead and Ringnecked duck females. In my opinion that isn´t an unusual thing for Aythya ducks in general. A small part of this may be indeed a result of genes from one species being brought into the gene pool by hybridisation (especially as ther eseems to be fertility in Aythya x Aythya hybrids) - but we do not know the exact amount.
However the bird posted by Bitis in my eyes clearly is some kind of hybrid with Pochard and Tufted duck genes to the following points: head is uniformely dark brown except for the pale area at the pase of the bill, and the border between pale and dark is sharp.
Also the mantle /scapulars are clearly darker than the flanks if you look at the series of photos. The third point is that the bird has a bill with a large pale area after the dark tip, getting darker towards the base of the bill. but under these light conditions in nearly all common pochards the bill would look all black with a pale area behind the tip
Certainly Pochard especially in autum to spring show pale in the face, but the face is getting gradually lighter towards the base of the bill, while in the hybrids this is a sharper , clearer border in most cases.
I personally think this is due to a difference in how the lighhter feathering arond the base of the bill is built up in the hybrids. In general there are whole white feathers (or as here, pale brown feathers-maybe due to staining?) around the base of the bill, often in a dense sharply demarcated patch, but sometimes also only dsome mixed in among colored feathers. This seems to be a bit similar to that what we get in the Canada goose x Greylag goose crosses, where you have also white feathering around the base of the bill- but a huge variation of it within individual birds (and there it is all first generation crosses , as there is no really proven fertility of the hybrids). This is the same in pochard x Tufted duck crosses, some only have a few single white featehrs there , others a large white area - but it also seems to be more pronounced in the winter birds. The white area around the bill in the scaups also seems to be similar to what is expressed in most hybrids tufted /pochard- a patch of white feathers.
Below this you can have also a pochard-like head pattern in some hybrids (but in general darker than in pochard), which can overlap ewith the white area.
(Something also seems to happen with the greyness of upper parts and flank. hybrids as well as pure birds tend to be browner in summer than in autumn/winter/ spring. In Aythyas the greyish coloration seems to be achieved by tiny pale spotting on the feathers which is more dense towards the featehr tip... I think abrasion may be involved here if birds get browner in summer... but in most hybrid sthis pattern is less dense on the mantle/scapulars than in teh flanks, whereas in most pochards the density of the pale stpots is ratehr similar on flanks and mantle/scapulars )
Some further Tufted x Pochard examples, together to the ones that have already been posted :
Macaulay Library ML140153191; © Dominic Mitchell; London, England, United Kingdom
macaulaylibrary.org
Macaulay Library ML613636922; © Alan Wilkinson; London, England, United Kingdom
macaulaylibrary.org
Macaulay Library ML627733491; © Magnus Andersson; London, England, United Kingdom
macaulaylibrary.org
Macaulay Library ML619779117; © David Darrell-Lambert; London, England, United Kingdom
macaulaylibrary.org
Macaulay Library ML557963551; © Gabriel Jamie; London, England, United Kingdom
macaulaylibrary.org
I am not sure if I explained that properly - but I hope you will understand what I am trying to say. If not , just ask

Also just take a look at the huge variability of males in that common cross
I think it would be logical to assume variation is similarly huge in females , though more difficult to detect...
For male Aythya hybrids , but not tackling the full variation , the attached may be interesting, even though it is in German and already several years old ...